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Chemical Science Cover for Warwick Surface Chemists

The ability of a metal surface to act as a ligand has been suggested in the past, specifically in the allegory of the so called “surface trans-effect”. In this work, a combination of precise quantitative structural measurements and theoretical calculations indicate that the “surface trans-effect” is a true trans-effect as observed in coordination chemistry, and the surface does indeed act as if it were a ligand. However, rather than the locally bound atomic electrons being the source of this phenomenon, it is the delocalised metallic electrons that are participating in this ligand-like interaction.

The cover and article are available as open access (CC-BY) documents

Image credit: Mrs. Claire Rochford

Tue 23 Aug 2016, 14:16 | Tags: publications MatPolymers